循環農業:農業廢棄物高價值化【李進發特聘教授】
論文篇名 英文:Visible-Light Photoredox-Catalyzed Thioacetalization of Aldehydes Under Metal-Free and Solvent-Free Conditions
中文:無金屬和無溶劑條件下可見光光氧化還原催化醛的硫縮醛化
期刊名稱 Advanced Synthesis and Catalysis (4/71 =5.63%)
發表年份,卷數,起迄頁數 Adv. Synth. Catal. 2019, 361, 1597 – 1605
作者 Kai Du, Shao-Chien Wang, R. Sidick Basha, and Chin-Fa Lee
DOI  10.1002/adsc.201800999
中文摘要 在無金屬和無溶劑條件下,醛首次以可見光促進硫代縮醛化。
英文摘要 A first visible-light photoredox-catalyzed thioacetalization of aldehydes under metal-free and solvent-free conditions is described. Under blue LED irradiation, a reactive thiyl radical was initially generated through single-electron oxidation of thiol, which subsequently reacted with aldehydes to afford dithioacetals following a radical mechanism. The reaction proceeded under ambient conditions, and a wide range of acyclic and cyclic dithioacetal derivatives were afforded in good to excellent yields.