設施農業：智慧感測【化學系/葉鎮宇特聘教授】
| 論文篇名 | 英文：Double Fence Porphyrins that are Compatible with Cobalt(II/III) Electrolyte for High-EfficiencyDye-Sensitized Solar Cells 中文：用於高效率染料敏化太陽能電池的鈷（II/III）電解質相容的雙柵欄紫質 |
| 期刊名稱 | Angew.Chem. Int. Ed |
| 發表年份,卷數,起迄頁數 | 2021, 60, 4886-4893 |
| 作者 | Chen, Ching-Chin; Chen, Jia-Sian; Nguyen, Vinh Son; Wei, Tzu-Chien*; Yeh, Chen-Yu(葉鎮宇)* |
| DOI | 10.1002/anie.202013964 |
| 中文摘要 | 設計並合成了一系列新的雙柵欄紫質染料bJS1–bJS3，其中八個長烷氧基鏈連接到四個b-苯基上。還製備了單柵欄meso替代物mJS1–mJS3作為參考染料。染料bJS1–bJS3和mJS1–mJS3的功率轉換效率分別為8.03–10.69%和2.33–6.69%。基於光伏研究，雙柵欄紫質敏化劑的顯著電池性能可歸因於減少了染料聚集和增加了電荷複合率。值得注意的是，紫質bJS2和bJS3的效率高於基準YD2-o-C8（本工作中為9.83%），證明雙柵欄結構是一種有效的設計策略。 |
| 英文摘要 | A series of new double fence porphyrin dyes bJS1– bJS3, with eight long alkoxy chains attached to four b-phenyl groups, have been designed and synthesized. The single fence meso-substituted counterparts mJS1–mJS3 were also prepared as reference dyes.Dyes bJS1–bJS3 and mJS1–mJS3 exhibit power conversion efficiencies of 8.03–10.69%and 2.33– 6.69%, respectively. Based on photovoltaic studies, the remarkable cell performance of double fence porphyrin sensitizers can be attributed to reduced dye aggregation and a decreased charge-recombination rate. Notably, porphyrins bJS2 and bJS3 exhibit better efficiency than the benchmark YD2-o-C8 (9.83%inthis work), demonstrating that the double fence structure is a promising design strategy for efficiency. |
| 發表成果與本中心研究主題相關性 | 此成果發表對於氣候變遷下對於農業創新加值之科技研究推動台灣新興能源研究與能源建置與整合是非常重要的，鼓勵支持具前瞻性、創新性及國際性之研究計畫，並促進國內不同領域學者及國內外學者間之合作交流，追求卓越學術研究成果，提升我國永續農業創新發展之研究水準。 |
