循環農業:農業廢棄物高價值化【李進發特聘教授】
論文篇名 英文:Electrochemical Dehydrogenative Phosphorylation of Thiols
中文:硫醇的電化學脫氫磷酸化
期刊名稱 Organic Letters [IF=6.555; 2/57 =3.5% (Q1)]
發表年份,卷數,起迄頁數 2019, 21, 7833−7836
作者 Chung-Yen Li,You-Chen Liu, Yi-Xuan Li, Daggula Mallikarjuna Reddy, and Chin-Fa Lee(李進發)
DOI 10.1021/acs.orglett.9b02825
中文摘要 我們在此報告了一種通過電化學反應從膦酸酯和硫醇合成有機硫代磷酸酯的新方法。反應是無需添加氧化劑、過渡金屬鹼或鹼,室溫下的即可進行。
英文摘要 We report herein a new approach for the synthesis of organothiophosphates from phosphonates and thiols through electrochemical reaction. The reactions were conducted without the addition of oxidant, transition-metal base, or base at room temperature. This system has a good substrate scope and functional group tolerance. Aryl and alkyl thiols worked well with phosphonates to afford the corresponding organothiophosphates in good yields.