循環農業：農業廢棄物高價值化【李進發特聘教授】
論文篇名 英文：Nickel-Catalyzed Cross-Coupling of Aryl Redoxactive Esters with Aryl Zinc Reagents
中文：鎳金屬催化芳香族氧化還原活化酯搭配芳香族鋅試劑交互偶合反應
期刊名稱 ACS Catalysis [IF=12.221; 11/148 =7.43% (Q1)]
發表年份,卷數,起迄頁數 2019, 9, 8862−8866
作者 Bo-Hao Shih,R. Sidick Basha, and Chin-Fa Lee
DOI  10.1021/acscatal.9b02913
中文摘要 開展了使用氧化還原活性酯與芳基鋅試劑進行鎳催化的芳基-芳氧基C(sp2)−O自由基交叉偶聯反應。此方法開創了一種新的斷開連接方法以形成芳基芳基酯。
英文摘要 A nickel-catalyzed aryl−aroyloxyl C(s p2)−O radical cross-coupling reaction conducted using a redox active ester with aryl zinc reagent was developed. This method demonstrates a new disconnection approach for formation of aryl aryl esters. In the one-pot sequential process, the readily available aryl carboxylic acids can be converted into functionalized aryl aryl esters and heteroaryl esters. This protocol is amenable to the gram-scale synthesis. The present method has a wide substrate scope and high functional group tolerance.