循環農業：農業廢棄物高價值化【環境工程學系/林坤儀特聘教授】
| 論文篇名 | 英文：Enhanced catalytic conversion of 5- hydroxymethylfurfural to 2,5-diformylfuran by HKUST-1/TEMPO under microwave irradiation 中文：利用HKUST-1 / TEMPO在微波輻射下提高5-羥甲基糠醛催化轉化為2,5-二甲酰呋喃的能力 |
| 期刊名稱 | BIOMASS CONVERSION AND BIOREFINERY |
| 發表年份,卷數,起迄頁數 | 2020, inpress |
| 作者 | Lin, Jia-Yin; Thanh, Bui Xuan; Kwon, Eilhann; Lin, Kun-Yi Andrew(林坤儀)* |
| DOI | 10.1007/s13399-020-00648-7 |
| 中文摘要 | 為了開發更有效的將5-羥甲基糠醛（HMF）氧化為2,5-二甲酰呋喃（DFF）的方法，建議將基於Cu的金屬有機骨架HKUST-1與2,2,6,6-四甲基哌啶-1結合使用 微波（MW）下的-氧基（TEMPO）用於增強HMF氧化為DFF 與通過常規加熱（CH）氧化HMF相比，已證實微波可縮短反應時間（<1 h）並提高HMF轉化率（> 99％）和DFF的收率（> 99％）。 HKUST-1可在多個週期內重複使用MW進行HMF轉換。 這些結果表明，HKUST-1是高效的HMF轉化催化劑，MW進一步提高了HMF轉化率，並顯著提高了DFF的收率。 |
| 英文摘要 | For developing more effective oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-diformylfuran (DFF), a Cu-based metal organic framework, HKUST-1, is proposed to incorporate with 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) under microwave (MW) for enhancing HMF oxidation to DFF. In comparison to oxidation of HMF by a conventional heating (CH), MW is validated to shorten reaction time (< 1 h) and enhance HMF conversion (> 99%) and yield of DFF (> 99%). HKUST-1 is reusable for HMF conversion using MW over multiple cycles. These results indicate that HKUST-1 is a highly effective catalyst for HMF conversion, and MW further enhances HMF conversion and increases yield of DFF significantly. |
